Preparation and luminescence performance of phosphor@SiO<sub>2</sub> aerogel composite luminescent material for laser illumination

Feng Jie; Gao Yan; Zhu Jiayi; Bi Yutie; Ren Hongbo

doi:10.11884/HPLPB202436.240010

Article Contents

Article Navigation > High Power Laser and Particle Beams > 2024 > Corrected proofs

Feng Jie, Gao Yan, Zhu Jiayi, et al. Preparation and luminescence performance of phosphor@SiO2 aerogel composite luminescent material for laser illumination[J]. High Power Laser and Particle Beams. doi: 10.11884/HPLPB202436.240010

Citation:

Feng Jie, Gao Yan, Zhu Jiayi, et al. Preparation and luminescence performance of phosphor@SiO₂ aerogel composite luminescent material for laser illumination[J]. High Power Laser and Particle Beams. doi: 10.11884/HPLPB202436.240010

Citation:

PDF( 10741 KB)

Preparation and luminescence performance of phosphor@SiO₂ aerogel composite luminescent material for laser illumination

doi: 10.11884/HPLPB202436.240010

Feng Jie^1
,,
Gao Yan¹,
Zhu Jiayi¹,
Bi Yutie¹,
Ren Hongbo^{1, 2
,
,}

1.
Joint Laboratory for Extreme Conditions Matter Properties, School of Mathematics and Physics, Southwest University of Science and Technology, Mianyang 621010, China
2.
State Key Laboratory of Environment-friendly Energy Materials, Southwest University of Science and Technology, Mianyang 621010, China

Received Date: 2024-01-05
Accepted Date: 2024-03-11
Rev Recd Date: 2024-03-11

Available Online: 2024-03-19

Abstract

Abstract

The preparation of Tb₃Al₅O₁₂ (TAG) phosphors was fabricated by the sol-gel method. Thermal analysis data confirm that an increase in the H₃BO₃ molar ratio correlates with a reduction in the transition temperature of the final phase. Concurrently, scanning electron microscopy revealed that an elevated H₃BO₃ molar ratio results in larger phosphor particle sizes. Under the excitation wavelength of 275 nm, the emission spectrum manifests multiple peaks within the 480-650 nm range, originating from the 5d→4f transitions of Tb³⁺ ions. Subsequently, the phosphor@SiO₂ aerogel composite luminescent material was successfully synthesized through a combination of physical doping and a supercritical drying process. This composite luminescent material exhibited a substantial increase in the internal quantum yield, reaching 63.64% compared to the standalone phosphor. Excited by a 355 nm laser source, the phosphor@SiO₂ aerogel composite luminescent material demonstrated the capability for wire-free, long-distance luminescence with commendable uniformity. These findings demonstrate the potential application prospects of the phosphor@SiO₂ aerogel composite luminescent material in the domain of laser emergency lighting.
- sol-gel method,
- TAG phosphor,
- phosphor@SiO₂ aerogel composite luminescent material,
- internal quantum yield,
- laser source excitation

FullText(HTML)

References(37)

References

[1]	卢锋. 地铁区间隧道消防应急照明与疏散指示系统设计研究[J]. 城市轨道交通研究, 2023, 26(s2):128-134 Lu Feng. Design study of fire emergency lighting and evacuation indication system for metro interval tunnel[J]. Urban Mass Transit, 2023, 26(s2): 128-134
[2]	王欢, 司镇, 李明进. 高层建筑应急照明设计分析[J]. 光源与照明, 2023(6):46-48 Wang Huan, Si Zhen, Li Mingjin. Analysis of high-rise building emergency lighting design[J]. Lamps & Lighting, 2023(6): 46-48
[3]	Hasirci Tugcu Z, Cavdar I H. A novel emergency lighting system design eliminating extra phase line installation[J/OL]. IETE Journal of Research, 2023, 69: 1-10(2023-02-12). https://www.tandfonline.com/doi/full/10.1080/03772063.2023.2173675.
[4]	Saito M, Kondo H. Battery-independent emergency illumination with RGB phosphors[J]. IEEE Aerospace and Electronic Systems Magazine, 2007, 22(2): 9-13. doi: 10.1109/MAES.2007.323293
[5]	Pinto R A, Cosetin m R, Campos A, et al. Compact emergency lamp using power LEDs[J]. IEEE Transactions on Industrial Electronics, 2012, 59(4): 1728-1738. doi: 10.1109/TIE.2011.2159352
[6]	Quintana-Barcia P, Ribas J, Juarez-Leon F A, et al. Permanent emergency LED lamp based on a series single-switch resonant converter with battery clamp[J]. IEEE Transactions on Industrial Electronics, 2022, 69(10): 9992-10000. doi: 10.1109/TIE.2021.3123649
[7]	李强, 郑静霞, 杨永珍, 等. 激光照明用荧光材料的研究进展[J]. 中国材料进展, 2023, 42(4):343-352 Li Qiang, Zheng Jingxia, Yang Yongzhen, et al. Research progress of fluorescent materials for laser lighting[J]. Materials China, 2023, 42(4): 343-352
[8]	王芬, 王丹. 激光照明与显示用荧光材料研究进展[J]. 中国材料进展, 2023, 42(4):289-295 Wang Fen, Wang Dan. Progress of phosphor materials for laser lighting and display[J]. Materials China, 2023, 42(4): 289-295
[9]	魏然. 激光照明与显示用荧光玻璃薄膜的光学特性研究[D]. 杭州: 中国计量大学, 2020: 1-51 Wei Ran. Optical properties of phosphor-in-glass films for laser lighting and display[D]. Hangzhou: China Jiliang University, 2020: 1-51
[10]	禹化龙. 高功率激光光纤远距离传输及光电转换技术研究[D]. 西安: 西安电子科技大学, 2022: 1-30 Yu Hualong. Research on high power laser over fiber long distance transmission and photoelectric conversion technology[D]. Xian: Xidian University, 2022: 1-30
[11]	Zhang Yunli, Hu Song, Wang Zhengjuan, et al. Pore-existing Lu₃Al₅O₁₂:Ce ceramic phosphor: an efficient green color converter for laser light source[J]. Journal of Luminescence, 2018, 197: 331-334. doi: 10.1016/j.jlumin.2018.01.014
[12]	Wang Jinchun, Tang Xueyuan, Zheng Peng, et al. Thermally self-managing YAG:Ce–Al₂O₃ color converters enabling high-brightness laser-driven solid state lighting in a transmissive configuration[J]. Journal of Materials Chemistry C, 2019, 7(13): 3901-3908. doi: 10.1039/C9TC00506D
[13]	Lin Tuan, Chen Hexin, Li Shuxing, et al. Bi-color phosphor-in-glass films achieve superior color quality laser-driven stage spotlights[J]. Chemical Engineering Journal, 2022, 444: 136591. doi: 10.1016/j.cej.2022.136591
[14]	Zhu Qiangqiang, Li Shuxing, Yuan Qiang, et al. Transparent YAG:Ce ceramic with designed low light scattering for high-power blue LED and LD applications[J]. Journal of the European Ceramic Society, 2021, 41(1): 735-740. doi: 10.1016/j.jeurceramsoc.2020.09.006
[15]	Ji Xiaofei, Du Yu, Zhang Xuetong. Elaborate size-tuning of silica aerogel building blocks enables laser-driven lighting[J]. Advanced Materials, 2022, 34: 2107168. doi: 10.1002/adma.202107168
[16]	李敏, 孙晓园, 范小暄, 等. Sr₆Lu₂Al₄O₁₅:Tb³⁺荧光粉的发光特性[J]. 发光学报, 2023, 44(11):1940-1949 doi: 10.37188/CJL.20230147 Li Min, Sun Xiaoyuan, Fan Xiaoxuan, et al. Photoluminescence properties of Sr₆Lu₂Al₄O₁₅:Tb³⁺ phosphor[J]. Chinese Journal of Luminescence, 2023, 44(11): 1940-1949 doi: 10.37188/CJL.20230147
[17]	孟晓燕, 廖云, 张丽蓉, 等. GdPO₄:Tb³⁺荧光粉的制备及发光性能研究[J]. 人工晶体学报, 2023, 53(1):107-114 Meng Xiaoyan, Liao Yun, Zhang Lirong, et al. Preparation and luminescent properties of GdPO₄:Tb³⁺ phosphors[J]. Journal of Synthetic Crystals, 2023, 53(1): 107-114
[18]	尹学爱, 吕树臣. Sr_0.3Ca_0.7MoO₄:Tb³⁺, Eu³⁺荧光粉的颜色可调发光和温度传感特性[J]. 发光学报, 2023, 44(4):607-614 doi: 10.37188/CJL.20220376 Yin Xueai, Lyu Shuchen. Color-tunable luminescence and temperature sensing behavior of Sr_0.3Ca_0.7MoO₄:Tb³⁺, Eu³⁺ phosphor[J]. Chinese Journal of Luminescence, 2023, 44(4): 607-614 doi: 10.37188/CJL.20220376
[19]	Ye Changwen. Ca₂MgSi₂O₇: Ce³⁺/Tb³⁺/Eu³⁺ phosphors: multicolor tunable luminescence via Ce³⁺ → Tb³⁺, Tb³⁺ → Eu³⁺ and Ce³⁺ → Tb³⁺ → Eu³⁺ energy transfers[J]. Journal of Luminescence, 2019, 213: 75-81. doi: 10.1016/j.jlumin.2019.05.004
[20]	Jiao Mengmeng, Yang Chuanlu, Li Yalin, et al. Potential color tunable Sr₃LaNa(PO₄)₃F:Eu²⁺/Tb³⁺/Mn²⁺ phosphor induced by Eu²⁺ → Tb³⁺ and Tb³⁺ → Mn²⁺ energy transfer for WLEDs[J]. Physical Chemistry Chemical Physics, 2017, 19(36): 24566-24573. doi: 10.1039/C7CP04691J
[21]	Duan Yutong, Zhao Chenyao, Lin Hui, et al. Photoluminescence properties of Tb₃Al₅O₁₂:Ce³⁺, Mn²⁺ phosphor ceramics for high color rendering index warm white LEDs[J]. Optical Materials, 2021, 111: 110670. doi: 10.1016/j.optmat.2020.110670
[22]	Mhin S W, Ryu J H, Kim K M, et al. Pulsed-laser-induced simple synthetic route for Tb₃Al₅O₁₂:Ce³⁺ colloidal nanocrystals and their luminescent properties[J]. Nanoscale Research Letters, 2009, 4: 888. doi: 10.1007/s11671-009-9331-9
[23]	Onishi Y, Nakamura T, Adachi S. Luminescence properties of Tb₃Al₅O₁₂ garnet and related compounds synthesized by the metal organic decomposition method[J]. Journal of Luminescence, 2017, 183: 193-200. doi: 10.1016/j.jlumin.2016.11.035
[24]	Oya T, Nakauchi D, Okada G, et al. Scintillation properties of Ce-doped Tb₃Al₅O₁₂[J]. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, 2017, 866: 134-139.
[25]	龚芮, 任洪波, 朱家艺, 等. 制备条件对溶胶凝胶制备Tb₃Al₅O₁₂:Ce³⁺荧光粉性能的影响[J]. 西南科技大学学报, 2017, 32(2):7-11,17 Gong Rui, Ren Hongbo, Zhu Jiayi, et al. Effect of fabrication conditions on properties of Ce³⁺ doped terbium aluminum garnet phosphor by sol-gel method[J]. Journal of Southwest University of Science and Technology, 2017, 32(2): 7-11,17
[26]	Nag A, Kutty T R N. Role of B₂O₃ on the phase stability and long phosphorescence of SrAl₂O₄:Eu, Dy[J]. Journal of Alloys and Compounds, 2003, 354(1/2): 221-231.
[27]	秦宇星. SrAl₂O₄:Eu²⁺, Dy³⁺长余辉光致发光材料的制备及其硼掺杂作用机理[D]. 天津: 天津大学, 2006: 1-44 Qin Yuxing. Preparation of SrAl₂O₄: Eu²⁺, Dy³⁺ phosphor and the effect of born substitution[D]. Tianjin: Tianjin University, 2006: 1-44
[28]	Choi T Y, Song Y H, Lee H R, et al. The effect of AlN and flux addition on luminescence properties of Ce doped TAG phosphor for white light emitting diodes[J]. Materials Science and Engineering:B, 2012, 177(7): 500-503. doi: 10.1016/j.mseb.2011.10.005
[29]	Witkiewicz-Lukaszek S, Gorbenko V, Zorenko T, et al. Epitaxial growth of composite scintillators based on Tb₃Al₅O₁₂:Ce single crystalline films and Gd₃Al_2.5Ga_2.5O₁₂ : Ce crystal substrates[J]. CrystEngComm, 2018, 20(28): 3994-4002. doi: 10.1039/C8CE00536B
[30]	Shabir H, Lal B, Rafat M. Sol–gel synthesis of Eu³⁺:Tb₃Al₅O₁₂ nanophosphor[J]. Journal of Sol-Gel Science and Technology, 2010, 53(2): 399-404. doi: 10.1007/s10971-009-2109-9
[31]	Batentschuk M, Osvet A, Schierning G, et al. Simultaneous excitation of Ce³⁺ and Eu³⁺ ions in Tb₃Al₅O₁₂[J]. Radiation Measurements, 2004, 38(4): 539-43.
[32]	Onishi Y, Nakamura T, Adachi S. Photoluminescence properties of Tb₃Al₅O₁₂:Ce³⁺ garnet synthesized by the metal organic decomposition method[J]. Optical Materials, 2017, 64: 557-563. doi: 10.1016/j.optmat.2017.01.024
[33]	Foster C, Koschan M, Wu Yuntao, et al. Boron codoping of Czochralski grown lutetium aluminum garnet and the effect on scintillation properties[J]. Journal of Crystal Growth, 2018, 486: 126-129. doi: 10.1016/j.jcrysgro.2018.01.028
[34]	Inkrataite G, Keil J N, Zarkov A, et al. The effect of boron and scandium doping on the luminescence of LuAG:Ce and GdAG:Ce for application as scintillators[J]. Journal of Alloys and Compounds, 2023, 966: 171634. doi: 10.1016/j.jallcom.2023.171634
[35]	Inkrataite G, Kemere M, Sarakovskis A, et al. Influence of boron on the essential properties for new generation scintillators[J]. Journal of Alloys and Compounds, 2021, 875: 160002. doi: 10.1016/j.jallcom.2021.160002
[36]	Poria K, Lohan R, Bhatia S, et al. Lumino-structural properties of Dy³⁺ activated Na₃Ba₂LaNb₁₀O₃₀ phosphors with enhanced internal quantum yield for w-LEDs[J]. RSC Advances, 2023, 13(17): 11557-11568. doi: 10.1039/D3RA01260C
[37]	Rajendran M, Vaidyanathan S. Systematic investigation of Eu³⁺ activated Na₂Ln₄(MoO₄)₇[Ln = La, Gd and Y] narrow band red emitting phosphors for hybrid white LEDs and plant growth[J]. New Journal of Chemistry, 2020, 44(35): 14823-14836. doi: 10.1039/D0NJ03766D