内嵌碳正八面体形貌Co<sub>3</sub>O<sub>4</sub>光催化活性研究

高立波; 张强; 徐宏妍; 第五江涛; 李俊漾; 张智博; 薛晨阳

doi:10.11884/HPLPB201527.024140

留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名

邮箱

手机号码

标题

留言内容

验证码

内嵌碳正八面体形貌Co₃O₄光催化活性研究

doi: 10.11884/HPLPB201527.024140

高立波^1,2,
张强^1,2,
徐宏妍³,
第五江涛³,
李俊漾^1,2,
张智博^1,2,
薛晨阳^1,2, ,

1.
中北大学仪器科学与动态测试教育部重点实验室, 太原 030051 ;
2.
中北大学电子测试技术国防科技重点实验室, 太原 030051 ;
3.
中北大学材料科学与工程学院, 太原 030051

详细信息

通讯作者:
薛晨阳

计量
- 文章访问数: 1773
- HTML全文浏览量: 260
- PDF下载量: 312
- 被引次数: 0
出版历程
- 收稿日期: 2014-09-08
- 修回日期: 2014-09-27
- 刊出日期: 2015-01-27

Photocatalytic activity of carbon-incorporated octahedral Co₃O₄_

1.
Key Laboratory of Instrumentation Science and Dynamic Measurement of Ministry of Education,North University of China,Taiyuan 030051,China;
2.
Science and Technology on Electronic Test &Measurement Laboratory,North University of China,Taiyuan 030051,China;
3.
School of Materials Science and Engineering,North University of China,Taiyuan 030051,China

摘要

摘要: 基于脱脂棉为牺牲模板,采用碳辅助法制备了内嵌碳的八面体形貌Co3O4,对其在模拟阳光下的光解水制氢气的能力进行了研究。X射线衍射（XRD）和扫描电镜（SEM）表征分析表明,制备的产物是具有规则正八面体形貌、粒径约为10 m的具有良好晶型的Co3O4。能谱（EDS）和光射线光电子能谱（XPS）结果表明,制备的产物内嵌无定形碳,碳源来自于脱脂棉制备过程中的不完全燃烧。实验结果表明制备的内嵌碳八面体形貌Co3O4具有良好的光解水制氢能力。
- Co3O4 /
- 脱脂棉 /
- 氢气 /
- 光催化
Abstract: Carbon-incorporated octahedral Co3O4 was synthesized via a novel and environment-friendly one-pot method using degreasing cotton as the sacrificial templates and its photocatalytic ability on producing H2 from water/ethanol solution under simulated solar light condition was investigated. X-ray diffraction (XRD) and scanning electron microscope (SEM) were performed to characterize the structure and morphology of the octahedral Co3O4 with a particle size of about 10 um. The energy dispersive spectrometer (EDS) manifested the incorporation of carbon species into octahedral Co3O4 and the X-ray photoelectron spectroscopy (XPS) confirmed that the carbon species come from the incomplete combustion of the degreasing cotton. The probable formation procedure of the carbon-incorporated octahedral Co3O4 was proposed. Notably, the resultant Co3O4 exhibited a promising capability on splitting water into H2.
- Co3O4 /
- degreasing cotton /
- hydrogen /
- photocatalytic activity