二氧化硅气凝胶微球制备技术
Fabrication of SiO2 aerogel microsphere
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摘要: 采用悬浊液成球技术制备低密度二氧化硅气凝胶微球,介绍了TEOS的水解、缩聚过程,主要论述了悬浊液成球技术、密度匹配技术、老化时间对微球性能,特别是收缩对微球密度的影响。实验制备了密度分别为70,100,150,200mg/cm3四种小球,结果表明:熟化时间取6d,制得的微球直径为0.1~2mm,密度为50~500mg/cm3,非球形参数为1.8%。Abstract: This paper presents the fabrication of lowdensity silicon dioxide aerogel microspheres and the sol-gel transition process. The work covers the effects of suspension spheres, the density-match and aging time on the properties of resultant aerogel spheres, focusing on the shrinkage effects. Four different density microspheres are studied with expected density of 70mg/cm3, 100mg/cm3, 150mg/cm3 and 200mg/cm3 respectively. The results show that we can obtain microspheres with diameter from 0.1mm up to 2mm, and density in the range of 50~500mg/cm3,and the parameter of out of round is 1.8%.
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Key words:
- silicon dioxide /
- aging /
- shrinkage /
- aerogel microsphere
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