Influence of water content on controlling parameters of morphology of TiO2 nanotube
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摘要: 以不同含水量的乙二醇溶液为电解液,采用阳极氧化法制备TiO2纳米管阵列。通过记录反应过程中电导率、粘度及回路电流随时间的变化曲线,研究含水量对电解液粘度、电导率及电流等过程参数的影响,分析了纳米管形貌尺寸与TiO2溶蚀所耗电荷量的关系。粘度初始值和初始电导率均与含水量呈三次关系,相关系数分别为0.992 5和0.977 8。在反应过程中,溶液粘度值有缓慢增加的趋势。由于不同含水量的电解液粘度的不同,H+和OH-数量不同,F-迁移速率不同,电导率-时间曲线及电流-时间曲线具有不同的变化趋势,并对其进行了理论分析。当水体积分数为4%,5%,6%和10%时,纳米管的形貌较为有序并且TiO2纳米管阵列表面的碎片较少,纳米管直径变化范围为50 nm至72 nm,长度变化范围为0.85~1.90 m。F-腐蚀氧化膜时所消耗电量与TiO2氧化膜被腐蚀掉的体积呈一次函数关系,即腐蚀电量越大,腐蚀掉的体积越大,为制备一定形貌尺寸的纳米管提供了一定的控制方法。Abstract: TiO2 nanotube arrays were fabricated by anodic oxidation of titanium foil in ethylene glycol electrolytes with different amount of water. The influences of water content on the conductivity, viscosity and current were studied by the curve of conductivity, viscosity and the loop current recorded online in the reaction process changing with time. The relationship between the dimension and the quantity of electric charge consumption of chemical dissolution of TiO2 oxide films was analyzed. The results show that cubics function relationship existed between viscosity and water content and between conductivity and water content. The correlation coefficients were 0.992 5 and 0.977 8, respectively. Viscosity of electrolyte increased slowly in the reaction process. Viscosity of electrolyte with different water content was not similar. Diversities in the number of H+ and OH- of electrolyte, as well as different transfer rate of F- resulted in the variation trends of current-time curve and conductivity-time curve. When the water content was 4%, 5%, 6% and 10%, the nanotubes morphology was highly in order and there was little debris on the surface of the TiO2 nanotube arrays. The nanotubes diameter was between 50 nm and 72 nm, and the length ranged from 850 nm to 1.90 m. The quantity of electric charge consumption of chemical dissolution of TiO2 oxide films in line with volume of TiO2 films dissolved in the electrolyte, the volume of TiO2 films dissolved increased with the increasing of the quantity of electric charge consumption of chemical dissolution of TiO2 oxide films, which provided a theoretical basis for the preparation of morphology and dimension controllable nanotube arrays.
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Key words:
- TiO2 /
- nanotube arrays /
- water content /
- morphology /
- control parameter
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