li liu-cheng, tang shu-kai, duo li-ping, et al. Experimental study on NCl3 spraying auto-decomposition[J]. High Power Laser and Particle Beams, 2007, 19.
Citation:
li liu-cheng, tang shu-kai, duo li-ping, et al. Experimental study on NCl3 spraying auto-decomposition[J]. High Power Laser and Particle Beams, 2007, 19.
li liu-cheng, tang shu-kai, duo li-ping, et al. Experimental study on NCl3 spraying auto-decomposition[J]. High Power Laser and Particle Beams, 2007, 19.
Citation:
li liu-cheng, tang shu-kai, duo li-ping, et al. Experimental study on NCl3 spraying auto-decomposition[J]. High Power Laser and Particle Beams, 2007, 19.
The spraying auto-decomposition of NCl3 was preliminarily investigated in a cylindrical gas flow tube. The red flame of NCl3 auto-decomposition by spraying was observed and its spectrum was measured. The spectrum was attributed to Cl2(B→X) transition. The decomposition mechanism of NCl3 molecule was discussed. It was believed that the preliminary decomposition of NCl3 was induced by shockwave and then Cl and NCl2 radicals produced reacted with NCl3 to give sustained flame. The experimental results show that NCl3 auto-decomposition can produce a large amount of radicals to replace discharge or combustor as the source of chlorine atom.
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