Pohl Institute of Solid State Physics,Shanghai Key Laboratory of Special Artificial Microstructure Materials and Technology,Tongji University,Shanghai 200092,China
Carbon aerogels were prepared from resorcinol and formaldehyde via sol-gel process, high temperature carbonization and atmospheric pressure drying technology with solvent replacement. By changing the resorcinol-sodium carbonate molar ratio and the mass fraction of the reactants, resorcinol and formaldehyde, the pore structure of carbon aerogels can be controlled and the palladium-doped carbon aerogels were prepared. By transmission electron microscopy (TEM), X-ray diffraction (XRD) spectra, it is confirmed that the Pd exists in the skeleton structure of carbon aerogels as a form of nano simple substance pellet. The specific surface area is successfully raised by 2 times , and palladium-doped carbon aerogels with a specific surface area of 1 273 m2/g have been obtained by carrying out the a