Terahertz spectroscopic properties of cross-linked polystyrene
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摘要: 交联聚苯乙烯是一种热固性塑料，具有优异的介电特性和耐高压击穿能力等特性。采用基于太赫兹波空气电离相干探测法(THz-ABCD)的太赫兹时域光谱系统，测量了交联聚苯乙烯和聚苯乙烯样品在太赫兹的光谱特性，得到了其在2~13 THz频段的吸收系数、折射率等光学参数。研究结果表明：交联聚苯乙烯和聚苯乙烯的吸收谱形状相似，在6.6，9.8和12.25 THz等处存在多个吸收峰，但是交联聚苯乙烯的吸收系数在12 THz以下高于聚苯乙烯，在12 THz以上低于聚苯乙烯；交联聚苯乙烯的折射率高于聚苯乙烯，聚苯乙烯的折射率在1.58~1.59之间，交联聚苯乙烯的折射率在1.59~1.62之间。Abstract: Cross-linked polystyrene is a kind of thermosetting plastic with excellent dielectric properties and high breakdown voltage. We measured the terahertz spectra of cross-linked polystyrene and polystyrene using THz-TDS based on THz-ABCD(air biased coherent detector), and the absorption coefficients and refractive indexes in the range of 2-13 THz were obtained. The terahertz spectra of cross-linked polystyrene and polystyrene were similar, and there existed several absorption peaks such as 6.6 THz, 9.8 THz and 12.25 THz, the absorption coefficient of cross-linked polystyrene was higher than that of polystyrene below 12 THz but lower above 12 THz, the refractive index of cross-linked polystyrene (1.59-1.62) was higher than that of polystyrene (1.58-1.59).
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